pH - a more scientific definition

pH refers to the relative concentration of H+ ions in solution. The numerical value of the pH is the negative of the exponent of the molar concentration. Thus low pH values indicate high concentrations of H+ ions (acid), and high pH values indicate low concentrations.

Ionisation - the process of spontaneous ion formation

H2O > OH- + H+

In 1 litre of water about 1 water molecule out of each 550 million is ionised at any instant in time corresponding to 1/10,000,000 of a mole of H+ ions ( a mole is defined as the weight in grams that corresponds to to the summed atomic weights of all the atoms of a molecule - its molecular mass. In the case of H+ the molecular mass equals 1, and a mole of H+ ions would weigh 1 gram.) The molar concentration of hydrogen ions in pure water, 1/10,000,000 can be written more easily by employing exponential notation. - count the number of decimal places after the digit "1" in the denominator

[H+] = 1/10,000,000

Brackets are used to indicate the chemical concentration of H+ . since there are 7 decimal places the molar concentration is 10 -7 moles per litre.

Any substance that dissociates to form H+ ions when dissolved in water is called an acid. The exponents in the exponential notation of H+ ion concentration are used as a convenient indication of acid strength called the pH scale. pH is normally expressed as a positive number and is the negative of the exponent of the molar concentration.

Pure water has a molar H+ concentration of 10 -7 and so a pH value of 7. The stronger the acid the more H+ ions it produces and so the lower its pH.

 


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pH - a more scientific definition
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pH refers to the relative concentration of H+ ions in solution. The numerical value of the pH is the negative of the exponent of the molar concentration. Thus low pH values indicate high concentrations of H+ ions (acid), and high pH values indicate low concentrations...

H+ ion
concentration
(moles/litre)

value

examples

OH- ion pH
concentration
(moles/litre)

10

-1

nitric acid

10-15

1

0

hydrochloric acid

10-14

10-1

1

stomach acid

10-13

10-2

2

lemon juice

10-12

10-3

3

vinegar,coca-cola

10-11

10-4

4

tomatoes

10-10

10-5

5

black coffee, normal rainwater

10-9

10-6

6

urine

10-8

10-7

7

pure water blood 10-7 tears

10-7

10-8

8

seawater

10-6

10-9

9

baking soda

10-5

10-10

10

great salt lake

10-4

10-11

11

household ammonia

10-3

10-12

12

bicarbonate of soda

10-2

10-13

13

oven cleaner

10-1

10-14

14

sodium hydroxide

1

10-15

15

drain opener

10

 


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